DYEINGS 

ON  UNION  SHODDY  CLOTH 


CASSELLA  COLOR  COMPANY 

182  and  184  Front  Street, 

NEW  YORK. 

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Montreal, Canada, 59. William  Street. 


No.  3454 


Franklin  Institute  Library 


PHILADELPHIA 


Class  £>.h~7. 2- 


Book..L...C1.2.. 

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REFERENCE 


GIVEN  BV 


orn 


DYEINGS 

ON  UNION  SHODDY  CLOTH 


TRADE- 


CASSELLA  COLOR  COMPANY 


182  and  184  FRONT  STREET 

' "N'E\r  YORK  • 

BOSTON':  39  xclive^s^re^t  • >»’»>]■  /’>, 
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MONTREAL:  Canada:  59  william  street. 


No  3454. 


DIRECTIONS  FOR  DYEING. 


1.  Self  Shades. 

Dyeings  Nos  1 — 48. 

Dyed  with  the  addition  of  2 lbs  Glauber’s  salt  crystals  per  10  gallons 
liquor  in  a boiling  hot  bath.  No  32  dyed  in  a cold  bath. 

Dyeings  Nos  49 — 64. 

Dyed  in  an  acid  bath  in  the  manner  customary  for  Acid  Colours. 

2.  Neutral  One-Bath  Dyeings  on  Unstripped  Material. 

Dyeings  Nos  66 — 76. 

Dye  in  as  short  a bath  as  possible  with  the  addition  of  1 — 2 lbs 
Glauber’s  salt  crystals  per  10  gallons  liquor.  Enter  hot,  and  dye  in  the  first 
instance  for  y2  to  % hour  near  boiling  temperature;  if  the  wool  is  then  found 
to  be  insufficiently  dyed,  boil  for  some  time  according  to  requirement;  a 
prolonged  boiling  should  however  be  avoided,  as  the  shoddy  wool  in  such 
case  readily  absorbs  the  dyestuff  and  turns  out  too  dark.  In  case;  the  cotton 
as  a result  of  prolonged  boiling  is  too  light  as  compared  with  the  wool,  the 
goods  should  be  allowed  to  run  for  some  while  longer  in  the  cooling  bath,  or 
the  requisite  amount  of  cotton  dyestuff  should  be  subsequently  added  if  neces- 
sary, without  heating  any  further. 

3.  Neutral  One-Bath  Dyeings  on  Stripped  Material. 

A.  On  Material  Stripped  with  Hyraldite. 

Dyeings  Nos  79 — 82. 

Dye  in  the  manner  indicated  for  Nos  66 — 76,  care  being  taken  that  the 
wool  is  very  well  rinsed  and  neutralised  before  dyeing;  it  will  in  most  cases 
not  be  necessary  to  boil  during  the  dyeing,  as  the  wool  absorbs  the  dyestuffs 
more  readily  when  the  material  is  stripped  than  when  unstripped. 

Dyeings  Nos  85 — 88. 

In  order  to  obtain  as  bright  shades  as  possible  on  the  stripped 
material,  the  wool  is  frequently  boiled  in  the  first  place  with  neutral-dyeing 
wool  dyestuffs,  the  cotton  dyestuffs  being  added  subsequently;  by  such  means 
the  cotton  is  covered  very  satisfactorily.  Dye  for  y,  to  % hour  at  the  boil 
with  the  wool  dyestuffs  suitable  for  the  purpose,  with  the  addition  of  1 — 2 lbs 
Glauber’s  salt  crystals  per  10  gallons  liquor,  shut  off  steam,  add  the  Diamine 
Colours  previously  well  dissolved,  and  cotton-dye  in  the  cooling  bath  for  % to 
% hour.  In  the  case  of  goods  containing  a great  many  burls  or  cotton  which 
is  difficult  to  dye,  the  cotton  is  frequently  covered  in  a weakly  alkaline  bath 
by  first  boiling  the  wool  and  then  cooling  the  bath  off  to  50 — 60°  C.  (120  to 
140°  F.),  and  thereupon  adding  the  Diamine  Colours  well  dissolved  as  well 
as  y% — 1 y2  oz  soda  ash  per  10  gallons  liquor. 


3 


B.  On  Material  Stripped  with  Bichrome  and  Sulphuric  Acid. 

Dyeings  Nos  91—94. 

After  rinsing  and  neutralising  tlie  goods  thoroughly,  dye  in  the  manner 
described  for  Nos  85 — 88  by  first  boiling  with  the  neutral-dyeiug  dyestuffs 
and  then  adding  the  Diamine  Colours  for  the  cotton  to  the  same  bath. 


4.  One-Bath  Weakly  Acid  Dyeings  on  Unstripped  Material. 

Dyeings  Nos  96 — 100. 

Goods  which  are  required  particularly  to  retain  their  quality  and  lustre, 
as  well  as  goods  containing  only  a slight  quantity  of  cotton,  may  also  be  dyed 
in  a weakly  acid  bath.  Dye  in  a short  bath,  with  the  addition  of  1 — 2 lbs 

Glauber’s  salt  crystals  per  10  gallons  liquor,  adding  besides  3 — 5%  sal 

ammoniac  or  acetate,  formate  or  sulphate  of  ammonia  (reckoned  on  the  weight 
of  the  goods  to  be  dyed).  Enter  the  goods  into  the  warm  bath,  raise 
gradually  to  the  boil,  and  boil  for  ^ to  1 hour  near  boiling  temperaure. 
Should  the  shade  of  the  wool  be  found  to  be  still  too  light,  the  boiling  may 

be  continued  for  a little  while  or  the  requisite  amount  of  wool  dyestuffs 

added,  the  treatment  being  continued  for  some  time  longer  near  boiling 
temperature.  If  on  the  other  hand  the  cotton  is  lighter  than  the  wool,  the 
requisite  quantity  of  Diamine  Colours  is  added,  the  goods  being  allowed  to 
run  in  the  cooling  bath. 


5.  Dyeing^the  Wool  Previously  with  Acid  Colours  and 
Cotton-Dyeing  Subsequently. 

Dyeings  Nos  102 — 112. 

The  brightest  and  clearest  shades  are  as  a rule  obtained  on  shoddy 
material  by  first  dyeing  the  wool  with  the  respective  Acid  Colours  (as 
shown  by  the  smaller  patterns)  and  cross-dyeing  the  cotton  in  a fresh  bath 
with  Diamine  Colours.  Dye  the  wool  first  in  an  acid  bath  in  the  customary 
manner  at  the  boil,  rinse  well,  and  cover  the  cotton  in  a fresh,  cold  bath  in  the 
vat,  or,  as  is  usually  preferred,  in  the  washing-machine  in  as  short  a liquor  as 
possible,  with  the  quantities  of  Diamine  Colours  mentioned  as  well  as  2 lbs 
Glauber’s  salt  crystals  and  if  necessary  % to  1 y2  oz  soda  ash  per  10  gallons 
liquor,  for  1 hour.  In  case  the  shade  of  the  cotton  is  too  light,  the  temperature 
should  be  carefully  raised  to  30 — 40°  C.  (85 — 105u  F.)  at  the  utmost,  or  some 
further  dyestuff  should  be  added  to  the  cold  bath.  The  cotton  is  thereby  in 
the  simplest  manner  dyed  to  the  same  shade  as  the  wool,  as  shown  by 
patterns  Nos  102 — 106,  or  black,  as  illustrated  by  Nos  107 — 112.  After 

rinsing  well,  treat  the  goods  with  a little  acetic  acid  in  the  last  rinsing 
bath,  and  dry  without  rinsing  again. 


6.  Dyeing  the  Wool  first  with  Acid  Colours  in  the  Stripping  Bath, 
and  Covering  the  Cotton  in  a Cold  Bath. 

Dyeings  Nos  115 — 124. 

In  the  case  of  a number  of  different  kinds  of  shoddy  materials,  the 
stripping  and  dyeing  can  take  place  in  the  same  bath.  According  to  the 
shade  desired,  boil  the  goods  first  for  y2  hour  either  with  sulphuric  acid 
alone  or  with  sulphuric  acid  and  bichrome.  Cool  off,  add  the  requisite 
quantity  of  suitable  Acid  Colours  to  the  same  bath,  and  bring  the 


4 


shade  of  the  wool  close  to  that  of  pattern  by  boiling,  care  being  taken 
thereby  to  keep  the  shade  just  a little  lighter  than  pattern,  as  is  shown 
by  the  small  patterns  in  the  card.  Any  of  the  easily  levelling  Acid  Colours 
are  suitable  for  the  previous  boiling  with  sulphuric  acid  by  itself,  whereas 
when  stripping  with  bichrome  and  sulphuric  acid,  the  following  dyestuffs, 
which  become  only  slightly  duller  by  being  used  in  such  stripping  bath, 
are  very  well  suited  for  the  purpose: 


Naphtol  Yellow  S 
Fast  Yellow-  S 
Acid  Y’ellow  AT 
Indian  Y'ellow  G,  R,  FF 
Orange  extra,  II 
Orange  EN,  ENZ 
Scarlet  FR,  F2R,  F3R 
Brilliant  Cochineal  2R,  4R 
Brilliant  Orseille  C 
Azo  Orseille  BB 
Acid  Magenta 


Acid  Violet  4RS,  6BS 
Alkaline  Violet  C,  CA 
Formyl  Violet  10B,  S4B 
Fast  Acid  Green  BN 
Cyanole  Fast  Green  G 
Acid  Green  extra  cone. 
Brilliant  Milling  Green  B 
Tetra  Cyanole  V,  SF,  extra,  A 
Cyanole  FF,  extra,  GG 
Formyl  Blue  B 
Brilliant  Milling  Blue  B 


After  dyeing  the  wool,  rinse  thoroughly,  and  cover  the  cotton  in  a fresh 
bath  with  the  addition  of  Glauber’s  salt  and  soda,  as  indicated  for  dyeings 
Nos  102—112. 


7.  Dyeing  the  Cotton  first  with  Black  Fast  to  Cross-Dyeing, 
and  Wool-Dyeing  with  Acid  Colours. 

A.  Dyeing  previously  in  the  Vat. 

Dyeings  Nos  126 — 130. 

For  deep  shades,  the  cotton  is  frequently  dyed  first  with  black  dyestuffs 
fast  to  acid  boiling,  the  wool  being  cross-dyed  subsequently  in  an  acid  ba.th. 
The  following  dyestuffs  are  suitable  for  dyeing  the  cotton  previously: 

Oxy  Diamine  Black  US  extra  cone.,  UI  extra  cone.,  SA  extra  cone. 

Para  Diamine  Black  BB  extra  cone.,  B extra  cone.,  FFB  extra  couc. 

and  BF  extra  cone. 

Diamine  Milling  Black  B cone.,  FG  extra  and  FFB  extra  cone. 

Charge  the  dyebatli  at  50 — 60°  C.  (120 — 140°  F.)  with  3 — 4%  dyestuff, 
2 lbs  Glauber’s  salt,  % — 1 y2  oz  soda  per  10  gallons  liquor,  and  dye  the  goods 
therein  for  % to  1 hour;  hereafter  rinse,  and  top  with  as  bright  Acid  Colours 
as  possible.  When  cross-dyeing,  care  has  to  be  taken  that  the  dyebath  reacts 
distinctly  acid  on  commencing  to  dye.  The  whole  of  the  acid  required  to 
make  the  dyestuff  go  on  to  the  fibre  is  added  to  the  dyebath  at  the  beginning 
of  the  dyeing  operation  already.  Enter  the  goods,  raise  to  the  boil,  and  boil 
until  the  liquor  is  exhausted;  if  the  liquor  is  insufficiently  acid,  the  dyestuff 
is  apt  to  come  off  the  cotton  again  in  the  boiling,  and  in  order  to  prevent 

this  as  much  as  possible,  it  is  well  in  addition  to  the  requisite  amount  of 

acid  to  add  about  5%  alum  to  the  acid  bath  for  dyeing  the  wool,  or,  the 
sulphuric  acid  or  bisulphate  of  soda  are  to  better  advantage  omitted,  2 — 3% 
formic  acid  and  5%  alum  or  sulphate  of  alumina  being  added  instead. 


5 


B.  Dyeing  the  Cotton  in  the  Milling  Process. 

Dyeings  Nos  132 — 136. 

For  certain  styles  the  cotton  can  be  dyed  previously  without  any 
special  dyeing  operation,  by  simply  adding  the  dyestuff,  previously  dissolved 
in  as  small  a quantity  of  boiling  water  as  possible,  to  the  soap  solution 
required  for  the  milling,  and  then  milling  the  goods  with  this  solution  of 
dyestuff  and  soap  in  the  customary  manner.  After  milling,  the  goods  are 
rinsed,  the  wool  being  then  cross-dyed  in  an  acid  bath  as  indicated  on  the 
previous  page  under  (A).  The  same  dyestuffs  come  into  consideration  for 
dyeing  during  the  milling  as  are  stated  under  (A)  for  the  previous  dyeing 
in  the  vat. 


8.  Cotton-Dyeing  Previously  with  Immedial  Carbon,  and 
Dyeing  the  Wool  Subsequently  with  Acid  Colours. 

Dyeings  Nos  138 — 142. 

In  order  to  obtain  dyeings  on  cotton  of  particularly  good  fastness  by 
the  simplest  method  of  working,  the  cotton  is  frequently  dyed  first  with 
Immedial  Carbon,  the  wool  being  then  cross-dyed  with  Acid  Colours  in  the 
customary  manner.  The  cotton-dyeing  in  such  case  is  done  in  a cold  or 
lukewarm  bath  either  in  the  jigger,  the  continuous  dyeing  machine  or  the 
padding  machine,  the  dyestuff  being  dissolved  in  a wooden  vessel  together 
with  the  amount  of  sodium  sulphide  requisite  for  the  dyeing  whilst  stirring 
well  and  this  solution  being  added  to  the  liquor  together  with  borax  and 
Glauber’s  salt. 

Charge  the  dyebath  in  the  jigger  per  10  gallons  liquor  with 

12  oz — 1 lb  Immedial  Carbon  B 

— 2 lbs  sodium  sulphide  crystals 
2 y2- — 3 lbs  borax 

3 lbs  Glauber’s  salt  crystals 
pass  the,  goods,  squeeze  off,  and  rinse  well. 

The  cross-dyeing  is  done  in  the  manner  customary  for  Acid  Colours. 
Hereafter  rinse  well,  and  aftertreat  in  the  last  rinsing  bath  with  4*4 — 9 oz 
acetate  or  formate  of  soda  per  10  gallons  liquor,  then  dry  without  further 
rinsing. 


The  quantities  indicated  for  dyeing  in  a neutral  bath  apply  for  the 
starting  bath,  correspondingly  smaller  quantities  being  required  when  dyeing 
on  a standing  bath. 


STRIPPING  OF  SHODDY  GOODS. 

Dark  shoddy  goods  are  stripped  with  a view  to  dyeing  light  or  full 
and  bright  shadqs  on  a dark  ground;  according  to  the  ground  shade  in  each 
case  and  the  degree  of  decolourisation  desired,  the  stripping  is  done  either 
with  bichrome  and  sulphuric  acid  or  Hyraldite. 


1.  Stripping  with  Biehrome  and  Sulphuric  Acid. 

Charge  a bath  of  about  GO0  C.  (140°  F.)  with 
2 — 4%  biehrome  and 
4 — 8%  sulphuric  acid, 

enter  the  goods,  raise  to  the  boil,  aud  boil  for  to  % hour.  Hereafter  rinse 
thoroughly,  and  dye. 

As  the  yellowish  bottom  obtained  in  this  manner  has  rather  a 
disturbing  effect  on  the  dyeing,  Ilyraldite  is  frequently  preferred  for  stripping, 
the  more  so  as  the  material  remains  in  better  condition  by  the  latter  method. 

2.  Stripping  with  Hyraldite. 

The  product  used  most  frequently  for  stripping  is  Hyraldite  Z for 
Stripping;  another  brand,  viz.  Hyraldite  Z soluble  cone.,  is  applied  in  the 
case  of  very  heavy  and  closely  woven  goods. 

A.  Stripping  with  Hyraldite  Z for  Stripping. 

According  to  the  depth  of  shade  of  the  ground  to  be  stripped  and  the 
effect  desired,  the  following  quantities  are  used: 

2 — 4 % Hyraldite  Z for  Stripping 

2.5 —  5.5%  formic  acid  85%  or 

1 — 2 % sulphuric  acid. 

B.  Stripping  with  Hyraldite  Z Soluble  cone. 

In  this  ease  the  following  are  the  quantities: 

1.5 —  3 % Hyraldite  Z soluble  cone. 

1 — 1-5%  formic  acid  85%. 

The  method  of  working  is  the  same  for  both  brands.  Charge  the  bath 
at  about  50°  C.  (120°  F.)  first  of  all  with  the  requisite  amount  of  Hyraldite, 
then  add  the  acid,  and  enter  the  goods  immediately  without  allowing  the 
bath  to  stand,  raise  gradually  to  the  boil,  and  boil  for  20  to  30  minutes.  If 
after  boiling  for  this  length  of  time  the  desired  effect  has  not  yet  been 
attained,  a little  Hyraldite  and  acid  are  further  added,  the  boiling  being  then 
continued  for  some  time  longer. 

The  stripping  proper  is  as  a rule  carried  out  in  a wooden  vat  kept 
specially  for  this  purpose,  the  steam-coils  contained  therein  being  to 
advantage  wrapped  round  with  cloth.  If  however  the  same  vat  is  to  be 
used  for  the  dyeing,  it  must  be  very  thoroughly  cleaned  beforehand  in  order 
to  completely  destroy  any  Hyraldite  left  therein,  so  that  it  may  not  exercise 
any  further  action  in  the  dyeing  which  follows. 

When  stripping  better-class  goods,  a little  monosolvol  (up  to  2% 
reckoned  on  the  weight  of  the  goods)  is  frequently  added  to  the  Hyraldite 
bath  in  order  that  the  wool  may  be  obtained  as  soft  as  possible.  After  the 
stripping,  the  goods  are  first  of  all  washed  thoroughly  in  cold  and  then  in 
warm  water. 

If  the  subsequent  dyeing  is  carried  out  in  a neutral  bath,  care  must 
be  taken  that  the  goods  are  completely  neutralised  previously,  which  is  best 
done  with  a little  soda  or  ammonia;  if  on  the  other  hand  the  stripped  goods 
are  to  be  cross-dyed  in  an  acid  bath,  it  is  sufficient  to  rinse  well. 


Without  guarantee. 


7 


i 


DIAMINE  COLOURS  (SELF  SHADES) 


3%  Oxy  Diamine  Yellow  TZ. 


3%  Diamine  Fast  Yellow  M. 


3%  Diamine  Orange  B. 


3%  Diamine  Brown  3G. 


3%  Diamine  Bordeaux  B. 


3%  Diamine  Bordeaux  S. 


11 


3%  Diamine  Violet  2205J. 


12 


3%  Diamiue  Violet  2204J. 


13 


3%  Dnlon  Blue  806.7. 


3% 


3%  Diamine  Green  B. 


Diamine  Bed  10B. 


3% 


Oxy  Diamine  Black  JB  extra  cone.  pat. 


16 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


3%  Diamine  Bed  4B. 


I 


DIAMINE  COLOURS  (SELF  SHADES) 


18 


19 


21 


3%  Diamine  Purpurine  6B. 


26 


3%  Diamine  Black  BIIF. 


27 


3%  Diamine  Black  BH. 


28 


3%  Oxy  Diamine  Blue  5G. 


29 


3%  Diamine  Sky  Blue  FF. 


30 


3%  Diamine  Black  HW  pat. 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


u 


DYESTUFFS  FOR  UNIONS 
(SELF  SHADES) 


NEUTRAL-DYEING  ACID  COLOURS 

(SELF  SHADES) 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


4%  Union  Brown  1926J. 


1.5%  Indian  Yellow  G. 


1.5%  Formyl  Violet  SIB. 


1.5%  Formyl  Blue  B. 


1.5%  Brilliant  Milling  Blue  B pat. 


1.5%  Brilliant  Milling  Green  B. 


1.5%  Alplianol  Blue  5KN. 


3%  Naphtylamine  Black  X3B. 


4%  Union  Brown  4221J. 


4%  Union  Brown  48S0J. 


4%  Union  Blue  4083 J. 


4%  Union  Blue  4669J. 


4%  Union  Blue  3S88J. 


4%  Diamine  Green  4419J. 


4%  Union  Green  34461. 


1.5%  Wool  Red  B. 


Ill 


51 


59 


2%  Orange  II. 


52 


2%  Scarlet  FR. 


53 


2%  Lanafuchsine  SG. 


54 


2%  Azo  Orseille  BB. 


2%  Cyanole  Green  B. 


60 


2%  Tetri  Cyanole  V. 


61 


2%  Cyanole  extra. 


62 


2%  Formyl  Violet  10B. 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


IV 


ONE-BATH  NEUTRAL  DYEINGS  ON  UNSTRIPPED  MATERIAL 


Iiaw  Material  for  Dyeings 
Nos  66 — 76. 

3 % 

Diamine  Fast  Yellow  M 

0.5  % 

Diamine  Black  HW  pat. 

0.15% 

Brilliant  Milling  Green  B. 

3.5  % 

Diamine  Black  BH 

2.5  % 

Formyl  Violet  10B. 

0.5  % 

Union  Brown  4354 J. 

3 % 

Diamine  Violet  2204J. 

0.25% 

Diamine  Fast  Yellow  M 

1.25% 

Diamine  Black  BH 

0.5  % 

Diamine  Green  B 

0.55% 

Brilliant  Milling  Green  B. 

66 


67 


69 


X/ 


70 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


v 


ONE-BATH  NEUTRAL  DYEINGS  ON  UNSTRIPPED  MATERIAL 


0.3  % Direct  Grey  2207J 
3 % Oxy  Diamine  Brown  BN. 


2.5  % Oxy  Diamine  Blue  5G 
0.12%  Diamine  Black  BH 
0.75%  Brilliant  Milling  Blue  B pat. 
0.2  % Brilliant  Milling  Green  B. 


71 


72 


0.75%  Oxy  Diamine  Black 

JB  extra  cone.  pat. 
0.7  % Diamine  Fast  Yellow  A 
0.02%  Brilliant  Milling  Green  B 
0.1  % Indian  Yellow  G. 


3.5  % Diamine  Bed  10B 
0.5  % Diamine  Bed  4B. 


0.75%  Oxy  Diamine  Black 

JB  extra  cone.  pat. 
0.05%  Brilliant  Milling  Blue  B pat. 


2.75%  Diamine  Black  BH 

1.5  % Alphanol  Blue  5BN 
1 % Formyl  Violet  S4B. 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


VI 


ONE-BATH  NEUTRAL  DYEINGS  ON  STRIPPED  MATERIAL 


Raw  Material  for  Dyeings 
Nos  79—82 


Patterns  for  Dyeings 
Nos  79 — 82 
stripped  with 

3 % Hyraldite  Z for  stripping  pat. 

2 % Sulphuric  Acid 

2 % Monosolvol. 


0.55%  Diamine  Orange  B 
0.02%  Diamine  Red  4B 
0.55%  Direct  Grey  2207J. 


0.3  % Diamine  Fast  Yellow  M 
0.4  % Diamine  Black  BIIF 
0.05%  Diamine  Orange  D 
0.08%  Brilliant  Milling  Green  B. 


4 % Diamine  Fast  Yellow  M 

0.16%  Union  Brown  TD  pat. 
0.45%  Diamine  Orange  B. 


0.5  % Diamine  Fast  Yellow  M 
0.3  % Oxy  Diamine  Blue  5G 
0.2  % Brilliant  Milling  Green  B. 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


ONE-BATH  NEUTRAL  DYEINGS  ON  STRIPPED  MATERIAL; 

THE  WOOL  BOILED  FIRST  WITH  NEUTRAL-DYEING  WOOL  DYESTUFFS 


Raw  Material  for  Dyeings 
Nos  85 — 88 


Patterns  for  Dyeings 
Nos  85 — 88 
stripped  with 

3 % Hyraldite  Z for  stripping  pat. 

4 % Formic  Acid  85%. 


1.5  % Indian  Yellow  G 

0.55%  Brilliant  Milling  Green  B 
0.25%  Oxy  Diamine  Brown  RN 
2 % Diamine  Fast  Yellow  A 

3.5  % Diamine  Black  HW  pat. 


1.5  % Wool  Red  B 

0.5  % Brilliant  Milling  Blue  B pat. 

3.5  % Diamine  Heliotrope  B 
0.35%  Diamine  Brown  M. 


86 


1.5  % Brilliant  Milling  Green  B 

3.5  % Diamine  Black  HW  pat. 

1 % Diamine  Fast  Yellow  A. 


87 


1.7  % Indian  Yellow  G 
1.2  % Oxy  Diamine  Brown  RN 
4 % Diamine  Fast  Yellow  A 

1.25%  Diamine  Black  HW  pat. 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


VIII 


ONE-BATH  NEUTRAL  DYEINGS  ON  STRIPPED  MATERIAL; 

THE  WOOL  BOILED  FIRST  WITH  NEUTRAL-DYEING  WOOL  DYESTUFFS 


Raw 

Material  for  Dyeings 
Nos  91—94 

Patterns  for  Dyeings 
Nos  91 — 94 
stripped  with 

2 % 

Bichrome 

4 % 

Sulphuric  Acid. 

0.5  % 

Brilliant  Milling  Green  B 

o.i  % 

Indian  Yellow  G 

1 % 

Diamine  Sky  Blue  FF 

© 

Ox 

sO 

Diamine  Fast  Yellow  A. 

0.3  % 

Formyl  Violet  S4B 

2.5  % 

Diamine  Heliotrope  B. 

0.25% 

Indian  Yellow  G 

0.02% 

Wool  Red  B 

1 % 

Oxy  Diamine  Brown  RN 

0.3  % 

Diamine  Black  RMW  pat. 

0.15% 

Indian  Yellow  G 

0.25% 

Wool  Red  B 

2 % 

Diamine  Red  10B 

0.15% 

Diamine  Brown  M. 

CASSELLA  COLOK  COMPANY,  NEW  YORK. 


IX 


WEAKLY  ACID  ONE-BATH  DYEINGS  ON  UNSTRIPPED  MATERIAL 


Raw  Material  for  Dyeings 
Nos  96 — 100 


2.5  % Diamine  Black  HW  pat. 

1.5  % Diamine  Fast  Yellow  M 
0.25%  Brilliant  Milling  Green  B. 


2 % Diamine  Bordeaux  B 

0.75%  Diamine  Bordeaux  S 
0.1  % Wool  Red  B. 


2.5  % Diamineral  Blue  CVB 
0.25%  Diamine  Heliotrope  B 
0.75%  Formyl  Blue  B. 


1.5  % Diamine  Brown  M 

1.2  % Diamine  Brown  3G 

0.2  % Diamine  Fast  Yellow  M. 


4 % Oxy  Diamine  Black  JB  extra 

cone.  pat. 

2 % Naphtylamine  Black  X3B. 


95 


96 


97 


98 


99 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


x 


WOOL-DYED  FIRST  IN  AN  ACID  BATH,  THEN  COTTON-DYED  COLD  TO  THE 

SAME  SHADE 


Raw  Material  for  Dyeings 
Nos  102—112 


1.75%  Formyl  Violet  S4B 


2 3/8  oz  Diamine  Black  BHF 
P/4  oz  Diamine  Purpurine  6B 

per  10 
• gallons 
liquor 

2 % Acid  Yellow  AT 

1 % Scarlet  Fll 

3 oz  Diamine  Orange  D 
3 dr.  Diamine  Purpurine  6B 

per  10 
• gallons 
liquor 

0.35%  Acid  Yellow  AT 
1.25%  Tetra  Cyanole  V 

ly2  oz  Diamine  Sky  Blue  FF 
3 oz  Diamine  Fast  Yellow  A 

per  10 
> gallons 
liquor 

2 % Formyl  Blue  B 

4J4  oz  Oxy  Diamine  Blue  5G 
ly  oz  Diamine  Black  BH 

per  10 
■ gallons 
liquor 

1.5  % Tetra  Cyanole  V 

3 oz  Diamine  Sky  Blue  FF 
% oz  Diamine  Fast  Yellow  A 

per  10 
gallons 
liquor 

CASSELLA  COLOR  COMPANY,  NEW  YORK. 


XI 


WOOL-DYED  FIRST  IN  AN  ACID  BATH,  THE  COTTON  THEN  DYED  BLACK 

IN  A COLD  BATH 


1 % 

Acid  Violet  6BS 

2 % 

Formyl  Blue  B 

5}4  oz  Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 

sP 

O'' 

CO 

© 

Cyanole  Green  B 

2.5  % 

Indian  Yellow  G 

1.5  % 

Lanafuchsine  SG 

4%  oz 

Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 

1.5  % Cyanole  Green  B 

0.3  % 

Acid  Violet  6BS 

4%  oz 

Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 

0.7  % 

Cyanole  Green  B 

0.12% 

Indian  Yellow  G 

0.32% 

Lanafuchsine  SG 

4%  oz 

Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 

3.5  % 

Cyanole  Green  B 

0.35 

Indian  Yellow  G 

4%  oz 

Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 

3 % Lanafuchsine  SG 


4%  oz  Diamine  Black  RMW  pat. 

per  10  gallons  liquor. 


107 


108 


112 


CASSELLA  COLOE  COMPANY,  NEW  YOEK. 


XII 


WOOL-DYED  FIRST  IN  THE  STRIPPING  BATH,  THEN  COTTON-DYED  IN 

A COLD  BATH 


Raw  Materia]  for  Dyeings 
Nos  115—124 


boiled  for  34 
2%  Bichromate  of  Potash 
6%  Sulphuric  Acid 
for  Nos  115,  118,  122, 
123,  124. 


hour  with 

6%  Sulphuric  Acid 
for  Nos  116,  117, 
119,  120,  121. 


0.1  % Tetra  Cyanole  V 
1.25%  Acid  Yellow  AT 
0.35%  Lanafuchsine  SG 

3 oz  Oxy  Diamine  Brown  RN 
% oz  Diamine  Fast  Yellow  A 
% oz  Diamine  Black  RMW  pat. 


0.9  % Cyanole  Green  B 
0.01%  Acid  Yellow'  AT 
0.4  % Lanafuchsine  SG 

1 oz  Diamine  Back  BH 

per  10  gallons  liquor. 


(per 
10  gallons 
liquor 


1 % Acid  Violet  4RS 

0.1  % Lanafuchsine  SG 


3 oz  Diamine  Heliotrope  B 
3/s  oz  Diamine  Black  RMW  pat 


per 

10  gallons 
liquor 


1.5  % Indian  Yellow  G 
0.2  % Acid  Green  extra  cone 


514  oz  Diamine  Fast  Yellow  A 
% oz  Diamine  Black  RMW  pat. 
2 3/s  oz  Diamine  Black  HW  pat. 


per 

10  gallons 
liquor 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


XIII 


WOOL-DYED  FIRST  IN  THE  STRIPPING  BATH,  THEN  COTTON-DYED  IN 
A COLD  BATH 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


1 % Acid  Yellow  AT 

2.15  % Cyanole  Green  B 


oz  Diamine  Sky  Blue  FF 
4 yx  oz  Diamine  Fast  Yellow  A 


per 

10  gallons 
liquor 


0.2  % Cvanole  Green  B 
0.19  % Lanafuchsine  SG 


1 oz  2 dr.  Diamine  Black  BH 
7 5/8  dr.  Diamine  Brown  M 
5!/s  dr.  Diamine  Fast  Yellow  Aj 


per 

10  gallons 
liquor 


1.25  % Formyl  Blue  B 
0.15  % Acid  Violet  4RS 


3 oz  Oxy  Diamine  Blue  5G 
2 oz  Diamine  Black  BHF 


per 

10  gallons 
liquor 


0.12  % Tetra  Cyanole  V 
0.08  % Acid  Yellow  AT 
0.16  % Lanafuchsine  SG 

1 oz  2 dr.  Diamine  Black  HW  pat.  1 per 
1 oz  14  dr.  Diamine  Brown  M / 10  gallons 

l%oz  Diamine  Fast  Yellow  aJ  liquor 


0.2  % Tetra  Cyanole  V 
0.17  % Acid  Yellow  AT 
0.75  % Lanafuchsine  SG 

3 oz  Diamine  Brown  M 

per  10  gallons  liquor. 


2 % Lanafuchsine  SG 


4 <4  oz  Diamine  Bed  10B 
yx  oz  Diamine  Brown  M 
% oz  Diamine  Black  BHF 


per 

10  gallons 
liquor 


XIV 


COTTON  FIRST  DYED  BLACK,  THEN  WOOL-DYED  IN  AN  ACID  BATH 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


Raw  Material  for  Dyeings 
Nos  126—130 


Cotton  for  Dyeings 
Nos  127 — 130  dyed  first,  with 
2.5  % Para  Diamine  Black  BF 

extra  cone  pat. 


2 % Acid  Green  extra  cone. 

1 % Indian  Yellow  G 


2 % Indian  Yellow  G 

0.75%  Azo  Orseille  BB 


3.5  % Cyanole  extra. 


XV 


COTTON-DYED  FIRST  IN  THE  MILLING  MACHINE,  THE  WOOL  THEN 

CROSS-DYED 


Raw  Material  for  Dyeings 
Nos  132—136 


Milled  for  Dyeings  Nos  133 — 136 
with  the  addition  of 
2 % Diamine  Milling  Black  FFB 

extra  cone. 

to  the  milling  liquor. 

2.5  % 

Naphtol  Yellow  S. 

1.75«/o 

Formyl  Violet  10B. 

3 % 

Naphtol  Yellow  S 

0.5  % 

Acid  Green  extra  cone. 

2.5  % Orange  IT. 


131 


132 


133 


CASSELLA  COLOE  COMPANY,  NEW  YORK. 


XVI 


COTTON-DYED  FIRST  WITH  IMMEDIAL  COLOURS,  THE  WOOL 
THEN  CROSS-DYED 


Raw  Material  for  Dyeings 
Nos  138—142 


Cotton  for  Dyeings 
Nos  139 — 142  dyed  first,  with 
12  oz  Immedial  Carbon  B 
per  10  gallons  liquor. 


2 % Orange  II. 


3 % Acid  Green  extra  cone. 

0.6  % Naphtol  Yellow  S. 


1.25%  Formyl  Violet  10B 
1 % Acid  Violet  6BS. 


3 % Alphanol  Black  3BN. 


137 


138 


139 


140 


141 


142 


CASSELLA  COLOR  COMPANY,  NEW  YORK. 


XVII 


RUSSIAN  ANILINE  COLOUR  WORKS  LEOPOLD  CASSELLA  & Co.,  RIGA 


SPECIAL- 


Works  at  Riga 


